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Supramolecular Complexes of Oxoporphyrinogens with Organic Molecules by V?clav B

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eBay item number:365700606708

Item specifics

Condition
Brand New: A new, unread, unused book in perfect condition with no missing or damaged pages. See all condition definitionsopens in a new window or tab
ISBN-13
9783031686450
Type
NA
Publication Name
NA
ISBN
9783031686450

About this product

Product Identifiers

Publisher
Springer
ISBN-10
3031686454
ISBN-13
9783031686450
eBay Product ID (ePID)
11069424708

Product Key Features

Book Title
Supramolecular Complexes of Oxoporphyrinogens with Organic Molecules
Number of Pages
Xv, 214 Pages
Language
English
Publication Year
2025
Topic
Physics / Magnetism, Physics / Atomic & Molecular, Physics / Nuclear
Illustrator
Yes
Genre
Science
Author
Václav BřEzina
Book Series
Springer Theses Ser.
Format
Hardcover

Dimensions

Item Length
9.3 in
Item Width
6.1 in

Additional Product Features

Dewey Edition
23
Number of Volumes
1 vol.
Dewey Decimal
547.1226
Table Of Content
Introduction.- Quantitative description ofsupramolecular binding.- Nuclear magnetic resonancespectroscopy.- UV/vis spectroscopy.- Singular value decomposition.- Chromic and binding propertiesof OxP derivatives.- Dynamic processes and chemicalexchange in OxP derivatives.- Conclusion.
Synopsis
Macrocyclic oxoporphyrinogen molecules combine the ability to form strong supramolecular complexes with organic compounds and the ability to absorb light. These properties allow high-sensitivity colorimetric detection of acids in solution in the presence of oxoporphyrinogen. Moreover, protonated oxoporphyrinogens show various molecular dynamic processes on the millisecond timescale. This book offers deep analyses of colorimetric, binding and kinetic properties of oxoporphyrinogen-acid complexes. A detailed introduction is given for: theory of supramolecular binding and chemical kinetics; NMR spectroscopy with emphasis on multi-state chemical exchange including derivation of analytical spectral lineshapes; UV/vis spectroscopy and analysis of UV/vis spectra, using singular value decomposition (SVD). Implementation of the derived models in Mathematica is also provided. The experimental part addresses SVD analysis of UV/vis spectra illuminating the effect of protonation on various oxoporphyrinogen derivatives and explaining the colorimetric response. Furthermore, analysis of chemical exchange lineshapes offers insight into the dynamic processes present in protonated oxoporphyrinogens. The various models and techniques described in this book are widely applicable for other systems.
LC Classification Number
QC170-197

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