Organometallic Chemistry of the Transition Metals by Robert H. Crabtree...

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Item specifics

Condition
Very Good: A book that has been read but is in excellent condition. No obvious damage to the cover, ...
Educational Level
Vocational School, Nursery School, Middle School, High School, Adult & Further Education
Personalized
No
Level
Technical, Business, Proficiency, Advanced, Intermediate, Beginner
MPN
N/A
Country/Region of Manufacture
United States
Unit Quantity
1
California Prop 65 Warning
N/A
ISBN
9780471662563
Category

About this product

Product Identifiers

Publisher
Wiley & Sons, Incorporated, John
ISBN-10
0471662569
ISBN-13
9780471662563
eBay Product ID (ePID)
43936923

Product Key Features

Number of Pages
560 Pages
Publication Name
Organometallic Chemistry of the Transition Metals
Language
English
Publication Year
2005
Subject
Chemistry / Inorganic, Chemistry / Organic
Features
Revised
Type
Textbook
Subject Area
Science
Author
Robert H. Crabtree
Format
Hardcover

Dimensions

Item Height
1.3 in
Item Weight
32.4 Oz
Item Length
9.4 in
Item Width
6.5 in

Additional Product Features

Edition Number
4
Intended Audience
Scholarly & Professional
LCCN
2005-277509
Reviews
"...one impressive and compressive book...this review would have to be book size to do full justice to all the insights in this volume." ( Journal of Metals Online , May 23, 3006)
TitleLeading
The
Dewey Edition
22
Illustrated
Yes
Dewey Decimal
547.056
Edition Description
Revised edition
Table Of Content
Preface. List of Abbreviations. 1 Introduction. 1.1 Werner Complexes. 1.2 The Trans Effect. 1.3 Soft Versus Hard Ligands. 1.4 The Crystal Field. 1.5 The Ligand Field. 1.6 Back Bonding. 1.7 Electroneutrality. 1.8 Types of Ligand. 2 General Properties of Organometallic Complexes. 2.1 The 18-Electron Rule. 2.2 Limitations of the 18-Electron Rule. 2.3 Electron Counting in Reactions. 2.4 Oxidation State. 2.5 Coordination Number and Geometry. 2.6 Effects of Complexation. 2.7 Differences between Metals. 2.8 Outer-Sphere Coordination. 3 Metal Alkyls, Aryls, and Hydrides and Related I?-Bonded Ligands. 3.1 Transition Metal Alkyls and Aryls. 3.2 Related I?-Bonded Ligands. 3.3 Metal Hydride Complexes. 3.4 I? Complexes. 3.5 Bond Strengths for Classical I?-Bonding Ligands. 4 Carbonyls, Phosphine Complexes, and Ligand Substitution Reactions. 4.1 Metal Complexes of CO, RNC, CS, and NO. 4.2 Phosphines and Related Ligands. 4.3 Dissociative Substitution. 4.4 Associative Mechanism. 4.5 Redox Effects, the I Mechanism, and Rearrangements in Substitution. 4.6 Photochemical Substitution. 4.7 Steric and Solvent Effects in Substitution. 5 Complexes of I?-Bound Ligands. 5.1 Alkene and Alkyne Complexes. 5.2 Allyl Complexes. 5.3 Diene Complexes. 5.4 Cyclopentadienyl Complexes. 5.5 Arenes and Other Alicyclic Ligands. 5.6 Metalacycles and Isoelectronic and Isolobal Replacement. 5.7 Stability of Polyene and Polyenyl Complexes. 6 Oxidative Addition and Reductive Elimination. 6.1 Concerted Additions. 6.2 SN2 Reactions. 6.3 Radical Mechanisms. 6.4 Ionic Mechanisms. 6.5 Reductive Elimination. 6.6 I?-Bond Metathesis. 6.7 Oxidative Coupling and Reductive Cleavage. 7 Insertion and Elimination. 7.1 Reactions Involving CO. 7.2 Insertions Involving Alkenes. 7.3 Other Insertions. 7.4 I?, I?, I?, and I' Elimination. 8 Nucleophilic and Electrophilic Addition and Abstraction. 8.1 Nucleophilic Addition to CO. 8.2 Nucleophilic Addition to Polyene and Polyenyl Ligands. 8.3 Nucleophilic Abstraction in Hydrides, Alkyls, and Acyls. 8.4 Electrophilic Addition. 8.5 Electrophilic Abstraction of Alkyl Groups. 8.6 Single-Electron Transfer Pathways. 8.7 Reactions of Organic Free Radicals with Metal Complexes. 9 Homogeneous Catalysis. 9.1 Alkene Isomerization. 9.2 Alkene Hydrogenation. 9.3 Alkene Hydroformylation. 9.4 Hydrocyanation of Butadiene. 9.5 Alkene Hydrosilation and Hydroboration. 9.6 Coupling Reactions. 9.7 Surface and Supported Organometallic Catalysis. 10 Physical Methods in Organometallic Chemistry. 10.1 Isolation. 10.2 1H NMR Spectroscopy. 10.3 13C NMR Spectroscopy. 10.4 31P NMR Spectroscopy. 10.5 Dynamic NMR. 10.6 Spin Saturation Transfer. 10.7 T1 and the Nuclear Overhauser Effect. 10.8 Isotopic Perturbation of Resonance. 10.9 IR Spectroscopy. 10.10 Crystallography. 10.11 Other Methods. 11 Metal-Ligand Multiple Bonds. 11.1 Carbenes. 11.2 Carbynes. 11.3 Bridging Carbenes and Carbynes. 11.4 N-Heterocyclic Carbenes. 11.5 Multiple Bonds to Heteroatoms. 12 Applications of Organometallic Chemistry. 12.1 Alkene Metathesis. 12.2 Dimerization, Oligomerization, and Polymerization of Alkenes. 12.3 Activation of CO and CO2. 12.4 CH Activation. 12.5 Organometallic Materials and Polymers.
Synopsis
Fully updated and expanded to reflect recent advances, this Fourth Edition of the classic text provides students and professional chemists with an excellent introduction to the principles and general properties of organometallic compounds, as well as including practical information on reaction mechanisms and detailed descriptions of contemporary applications.
LC Classification Number
QD411.8.T73C73 2005

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